Reaction of Aromatic Hydrocarbon Disodium Complexes with Butadiene in Liquid Ammonia

Phase transfer catalyzed reaction of disodium salt of 1,3-dihydroxybenzene with propargyl bromide in solid-liquid biphasic condition

The present work describes, the reaction between disodium salt of 1,3-dihydroxybenzene (in situ formation) and propargyl bromide was carried out in a solid-liquid biphasic phase transfer catalytic system at 50°C. Higher selectivity of the bis-derivative (1,3-bis(prop-2-ynyloxy)benzene) was obtained under solid-liquid PTC condion. The conversion of propargyl bromide of more than 99% was achieved...

Polycyclic Aromatic Hydrocarbon (PAH) formation in thermal degradation of Styrene Butadiene Copolymer (SBR)

This study has been initiated to quantify the release of the Polycyclic Aromatic Hydrocarbon (PAH) species from Styrene· Butadiene Copolymer (SBR) during gasification. The identification and quantification has been detennined experimentally using Gas Chromatography/ Mass Spectroscopy (GC/ MS) coupled to a Thenno-Gravimetric Analysis (TGA) unit. SBR samples were pyrolysed in a TGA unit in a Nz a...

Reversibility of Reaction of Potassium with Liquid Ammonia.

Ammoniated electrons exist in solutions of potassium amide in liquid ammonia which have reached thermodynamic equilibrium with hydrogen gas. By determining electron concentrations by electron spin resonance, an equilibrium constant of 10(5) at room temperature has been obtained.

Selective Liquid Phase Ammoxidation of Aromatic Aldehydes to Aromatic Nitriles with VPO Titania Heterogeneous Catalysts in Air

 Preparation of 2-Chlorobenzonitrile, and benzonitrile are reported here from the corresponding 2-Chlorobenzaldehyde and benzaldehyde by the reaction of ammonium hydroxide/VPO titania, VPO bulk (...

Comparison of aromatic hydrocarbon measurements